Under the same conditions, sure: both players must be using Excelsior cardpool decks, and each must post a decklist and link to it in an Excelsior forum post (the two players should coordinate on the same thread). We'll run this as a pilot program for Act I, and if players enjoy it, we'll add it to the VP Schedule.
(Also, take pics and post them! Adds to the fun when we can see what happened along with the game report.)
Here's what I posted regarding the Online League:
if two League players agree to play with Excelsior decks for a League match, and each can provide a decklist link in a post(s) that describes their game, those VPs will count towards their HQ total for the Excelsior Campaign. Both players must agree to participate in order for both players to score any Excelsior VPs.
To avoid potential abuse of this allowance, there will be an initial 10 VP cap per month for these types of games (players may not earn more than 10 VPs in a month this way via live or online non-tournament games).